ME 7771: Mechanics of Polymer Solids and Fluids
Offered Every Spring

 
Credit Hours:  3-0-3
Prerequisite:  Graduate standing in engineering or equivalent discipline
Catalog Description: 
Continuum mechanics of solids and fluids; mechanics of deformation of anisotropic polymers; anisotropy and critical phenomena, such as yield, breaking and fatigue; non-Newtonian viscous and viscoelastic behavior of polymer fluids. Crosslisted with CHE, MSE, and PTFE 7771.
Textbook:  Taught in ChE
Instructors:  A.S. Abhiraman (ChE), Karl Jacob (PTFE), Mary Lynn Realff (PTFE) (Summer 2004)

Goals:

  1. Learn the foundations of mechanics of large deformations in solids and non-Newtonian flow of fluids
  2. Learn the foundations in mechanics for developing structure-property relations in anisotropic bulk polymers
  3. Learn phenomenological continuum constitutive models in polymer fluids and solids
  4. Learn the distinctions between polymers and small molecular materials in critical mechanical phenomena (yield, fracture, fatigue, etc.)
Topic:
  1. Analysis of stresses in a medium
  2. Analysis of deformation in a medium

  3. a. finite strain
    b. small strain
  4. Linear and non-linear elasticity

  5. Constitutive relations for large elastic deformations; strain energy function and its relationship to stress tensor for large deformations; Relationships between continuum and molecular models of rubber elasticity
  6. Symmetry relations and material constants

  7. Covering operations for material symmetry; common symmetries in polymeric materials
  8. Anisotropic mechanical behavior of polymers

  9. Consequences of local and global symmetries in polymer morphology
  10. Yield behavior

  11. Classical theories of yielding; Hill’s yield criterion; brittle and ductile failures in polymers; molecular theories of yielding and cold drawing
  12. Breaking phenomena

  13. Classical theories of fracture; critical strain energy release rates in polymer fracture; crazing in polymers; molecular theories of fracture in polymers
  14. Fatigue

  15. Static and dynamic fatigue in polymers; empirical formulations; rate theories
  16. Framework of fluid dynamics

  17. Introduction to viscous Newtonian and non-Newtonian fluids
  18. Material functions for polymer fluids

  19. The concept of simple fluids; viscometric flows of simple fluids
  20. Flow phenomena in polymer fluids

  21. Experimental aspects of viscometric functions; flow phenomena on viscoelastic polymer fluids
  22. Generalized Newtonian fluids

  23. Ellis, power-law and other models; determination of shear viscosity function through capillary flow
  24. Linear viscoelastic fluids

  25. Simple and generalized Maxwell fluids; frame invariance requirements for costitutive equations
  26. Co-deformational and corotational models

  27. Maxwell-Oldroyd and Maxwell-Jaumann fluids; various modifications
  28. Dimensional analysis vis-a-vis non-Newtonian fluids

  29. Constitutive equations vis-a-vis dimensionless groups; applications to non-Newtonian viscous and viscoelastic fluids
Delivery mode (%):
 
Lecture 100%
Laboratory  
Supervised
 
Unsupervised
 
Discussion  
Demonstration  
Grading Scheme (%):  
Homework 10%
Individual Projects  
Exams 90%

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Revised July 2004